CPS bladders are primed before testing (i.e. removing the air inside the bladder), but the volume recorded is the amount of water pushed out not including any water that's left trapped within the bladder (dead volume). Total volume in most cases of a PC is usually larger than the PC volume reported on iSoaker.com since I only report what can be pushed through the nozzle.
The Pre-Charger series was the biggest pain to figure out how to best do PC measurements. In that particular case, the amount of water that can be pushed into the front side really depends on the position of the sliding piston is before the blaster pushes air to the back-side of the chamber. For sake of argument and consistency, I kept all blaster sliding pistons at their full-forward position, pre-pressurized the back side, then pushed water into the front side (priming the tubing to flush out any residual air trapped in tubing), then did the volume measurements. What one could do, though, is fill the front side with some water first (say 1/3), then do the pre-charging, then pump in more water to give one more available PC capacity and still be able to pretty much empty the PC. However, it would be very tricky to do this in a consistent for doing available PC volume measurements and chose to consider "stock" PC volume based on the amount pushed out following the instructions of pre-pressurizing first before pumping water.
You are absolutely right that full PC volume would be a nice number to have since available volume depends on PRV variability. However, getting that measurement properly would be more involved (best way would still be to dismantle the blaster and measure directly since other methods have no way to account for water trapped in tubing. As I, personally, prefer not to open blasters unless repair or really curious about their internals, I'll be sticking to simply measuring pushed water volumes for now (the easiest) and hoping that PRVs between blasters of the same model do not vary significantly (might be an additional 30ml/1oz. at most, but I'd be surprised if another stock blaster of the same model would differ much more in available PC volume than that due to its PRV).
All this said, I should probably put a note on the iSoaker.com reviews about all this stuff. I think parts of explained somewhere, but not all.
